Thursday, November 28, 2019
I Found It Very Difficult To View This Narrative As A Tragedy, Possibl
I found it very difficult to view this narrative as a tragedy, possibly due to my view that Medea was the Heroine and main character rather than Jason. From Jason's point of view it was truly a tragedy that his bride, children and successors were taken from him. However, I don't believe that this was a tragedy for Medea, but rather a personal story of an individual living her own will. Circumstances forced her to make a decision on her future, vowing to revenge her broken heart. Betrayed by her lover, Medea experienced feelings of hurt, anger and a desire for revenge. Once her mind was made up to strike back upon her assailant, all the details of her plan just fell into place. She was able to manipulate Jason, his new bride and the king into playing their parts in her scheme of bloody retribution. All the goals she set forth were accomplished; not however without pains. She was banished and was forced to murder her two children to attain her goal. Jason subjected her to a bottomless pain and she therefore grew stronger in order to survive. For her to continue she needed to leave her mark upon Jason. Murdering his bride, and Creon as an added bonus, got his attention. Followed by the dismembering act of murdering his children. Crippling his existence Medea had won. She would not be mocked. Multiple times she questions her morality on whether she could carry the plan out, but ultimately revenge was more important than her children or her way of life, due to the pain in her heart. I see that she made a large sacrifice to achieve revenge but surely this is no tragedy, not for her at least.
Monday, November 25, 2019
Aztec Empire essays
Aztec Empire essays Do Aztec Empire deserved to be destroyed? Is destruction of Tenochtitlan a loss to history? The Aztecs was a great empire in year 1519. They were very strong and their capital city Tenochtitlan was a huge city that built in the middle of the lake and it was man-made. Tenochtitlan was the largest city in the world at that time. But in 1521, the Spanish discovered the Aztec empire and destroyed all the things they had. Tenochtitlan was surrounded soon and the Aztecs were over. Aztecs people were clever and talented in same ways, but there were also ways that they were foolish and uncivilized. So I am going to talk about do the Aztec empire deserved to be destroyed, and is destruction of Tenochtitlan a loss to history. There were many ways that showed the Aztecs were talented and civilized. First, the Aztecs were skilled architectures, engineers, and designers, they could build huge city on the middle of a lake, they also building temples that surrounded the old ones when there is a new empire. The Aztecs were good farmers also, they were skilled to get water from mountains using irrigation even though Mexico is a dry country. Science and technology were also advanced in the Aztec Empire, people built gardens that contain natural medicines. All these evidences tell us that the Aztecs shouldnt deserve to be destroyed and the destruction of Tenochtitlan is a loss to history. Although the Aztec Empire had many ways that shown they didnt deserved to be destroyed, there were certain ways that tell us the Aztecs arent civilized and even very foolish in some ways. Religion was a very important part in the Aztec empire. The Aztecs people treated their god top of everything else and worship them blindly. The Aztecs would do anything to please their god, and even horrible and cruel things like human sacrifices. The priest would do human sacrifice in a cruelly by cut and taking a live mans heart out from his body. T ...
Thursday, November 21, 2019
Developing Management Skills Assignment Example | Topics and Well Written Essays - 1250 words
Developing Management Skills - Assignment Example The management style may end up frustrating the managerââ¬â¢s efforts in relation to deriving support from employees. Psychological resiliency is the ability to endure psychological risk factors/ stressors without exhibiting psychological dysfunction (such as post-traumatic stress disorder, PTSD). On the other hand, social resiliency is the ability to withstand stressors that emanate from the social and environmental spheres. In addition, social resilience is an analytical framework that emanates from the concept of social vulnerability whereas psychological resilience emanates from psychological stressors. Individuals can manage personal stress from the work-life balance by adopting the analytical framework that forms the foundations of social resiliency. The work-life balance entails the coping, adaptive, and transformative capacities that represent social resilience. Stress levels are significantly reduced when the work-life balance is approached with the three ââ¬Ëpillarsââ¬â¢ of social resiliency. Psychological resiliency is the best possible mechanism to respond to an experience of personal failure. For example, an individual may set performance benchmarks in his or her area of expertise. Such benchmarks could be accompanied by rewards. The benchmarks and rewards would act as intrinsic and extrinsic motivators of success in an attempt to erase the previous experience of personal failure. The analytical problem-solving approach commences with defining the problem. This step involves differentiating objective and subjective opinions while specifying the underlying causes of the problem. It is at this step that all the relevant parties are tapped for information to identify whose problem it is. In addition, this step avoids ambiguity on how the problem is presented. On the other hand, the creative problem-solving approach commences with preparation. This stage is simple and is limited by scope.Ã
Wednesday, November 20, 2019
Counseling Assignment Example | Topics and Well Written Essays - 2000 words
Counseling - Assignment Example I would start by asking the freshman the reasons as to why he chose the career. This can be due to personal interest on that area, persuasion/ influence from either parents or colleagues, being cheap in terms of cost, taking a short duration of time. It can even be that the freshman chose the career not basing it on any factors. My area of interest would be to ascertain the suitability of the career from the 'marketability' point of view. He should be able to choose a career that would enable him secure a job as soon as he finishes college. I would then encourage him to change his career if I realize that the one he has chosen may not adequately serve his needs as soon as he finishes college. I will stipulate to the freshman the need for living harmoniously with colleagues in college. Living peacefully with colleagues would enable him to always have a peaceful mind and be able to concentrate in his studies. Conflicts characterized with chaos, fights would not only adverse his performance in academics, but can make him either be suspended or expelled from college. The entire life of the freshman would be greatly influenced by the kind of people/ friends he would be associating himself with. Friends are people who can easily influence someone's character, either positively or negatively. I would therefore urge the freshman to carefully choose the kind of people to associate with. He can do this by consulting the sophomores and other seniors if the people he wants to associate himself with are already known by them (sophomores and seniors). If they are fresher, then he can use his own judgment to determine whether they are good or bad, morally upright or to the contrary etc. I would further advice him to cling to people with vision and one goal - that of passing college exams and coming out successfully. In this respect I would advice him to completely avoid associating himself with students who take alcohol, smoke, and who involve themselves in other immoral activities. 4) SEXUAL RESPONSIBILITY This would be a very important topic as far as the new freshman is concerned. I would tell him the need to completely abstain from sex. Sex, being addictive would deviate his mind from studies thus deteriorating his performance. It can also earn him enemies because he might be competing with his colleagues and even lecturers for sexual partners. Worst of all, I would highlight to him; the dangers of engaging in sex irresponsibly one of them being contracting of sexually transmitted diseases and HIV/ AIDS. 5) OBEDIENCE & ADHERENCE TO ESTABLISHED RULES I would advice the freshman to adhere to the generally established rules and regulations of the
Monday, November 18, 2019
Islamic Art Essay Example | Topics and Well Written Essays - 1000 words
Islamic Art - Essay Example For this reason, construction of mosques as well as other buildings related to religion was considered the responsibility of rulers of that time. Therefore, the patronage of caliphs played an important role in the development of early Islamic art forms. This patronage allowed the birth of Islamic architecture, the decoration of religious buildings and their furnishings; a trend that was previously unknown to the world. In contrast to the art forms of other regions which utilize sculptures or paintings as the predominant form of expression, the Islamic art utilizes decoration as a medium or art and expression. The initial manifestations of this type of art work are seen in monuments and mosques of those times, which portray decoration that is extraordinary and expensive in nature. Due to the vital position of mosques in the Islamic society, decoration as a medium of expression was applied on these buildings during the early period of Islamà (Lapidus 97). Another unique art form ter med calligraphy also started to evolve; this time into patterns that were not only meant to communicate the message of Islam, but also to contribute to the aesthetic value of mosques and other religious buildings. This decorative use of the sacred texts in buildings that was religious in nature paved way for various art forms that were aesthetically appealing to a wider audience. Hence calligraphy started finding place in objects like stone, wood, glass, pottery and textiles. Dome of the rock was built in the seventh century.
Friday, November 15, 2019
Surface Antigen of Apicomplexan Parasite, Eimeria Tenella
Surface Antigen of Apicomplexan Parasite, Eimeria Tenella INTRODUCTION Intestinal coccidiosis is caused by the intracellular growth and replication of coccidian (Shirley Schnitzler, 1999; Belli et al., 2006; Lim et al., 2012). Chicken has become the host to seven species Eimeria which are E. tenella, E. maxima, E. acervulina, E. brunette, E. necatrix, E. praecox, E. mitis and each species is responsible for a different form of coccidiosis. The three most pathogenic Eimeria species which cause the most economically significant are E. tenella, E. acervulina and E. maxima. Each parasite is responsible for a different form of coccidiosis (Shirley et al., 2004). Eimeria tenellacause coccidiosis in chickens which is a serious intestinal disease leading to impaired nutrient absorption, weight loss, diarrhea and severe cases of death (Belli et al., 2004). Ceacum is the part of intestinal tract location that will infected by E. tenella (Barta, 1997). On the other hand, three different phases of the life cycle of Eimeria are sporogony (the unsporulated oocysts s hed in the faeces of the host undergo sporulation in the environment to become infective), schizogony (an expansive form of asexual reproduction) and gametogony, a sexual phase (which leads to the formation of female and male gametes, and end with the formation of oocysts) (Shirley Schnitzler, 1999). The control of coccidiosis depends on prophylactic chemotherapy and also vaccination (Shirley et al., 2004). Whereas Mcpherson-K. J. L (2008) state that the current strategies to control coccidiosis in commercial poultry include anticoccidial medication, vaccination and also the use of probiotics. For a long-term control of coccidiosis, the identification of new targets within Eimerian parasite is required and this imperative underpins the need for the genome sequencing (Shirley et al., 2004). 1.1 PROBLEM STATEMENT Coccidiosis is one of the most important and common diseases that affect poultry, it results in a great economic loss all over the world (S. Al-Quraishy, A.S. Abdel-Baki,à M.A. Dkhil, 2009). It is caused by the genus Eimeria of an apicomplixa protozoan parasite (Shirley, 1995). This parasitic infection occurs in the epithelial cells of the intestine, despite the advances in nutrition, chemotherapy, management and genetics (Jamal Gharekhani, Zivar Sadeghi-Dehkordi, and Mohammadali Bahrami,2014). Most Eimeria species affect birds between 3 and 18 weeks of age and can cause high mortality in young chicks(McDougald and Reid, 1997). Eimeria typically infect defined regions of the gastrointestinal tract leading to impaired nutrient absorption, weight loss, diarrhea and in severe cases mortality (Belli et al., 2004). The poultry industry incurs major economic losses since chemoprophylaxis, the preferred method of preventing and controlling the disease, is ineffective because the resilient parasites do not respond to therapy. Infections of chickens begin after the uptake of oocysts when sporozoites penetrate the epithelium of the villi. They enter crypt epithelial cells after passing through the lamina propria, where they will undergo several rounds of asexual and sexual proliferation, resulting in formation of merozoites and later, gametocytes (Jeurissen SH, Janse EM,à Vermeulen AN,Vervelde L, 1996). When macrogametes are fertilized by microgametes, forming zygote that will develop into oocysts and eventually shed in the faeces. In contrast to the malaria parasites, Eimeria spp. has not been proved pathogenic for man. The organism has never been found in intestinal tissue and no specific lesion has been demonstrated. Many therapeutic agents have been used, including bismuth, iodide, quinine, gentian violet, emetine, anthelmintics and others without conclusive evidence of results (R. M. Kiskaddon, M.D.; R. J. F. Renshaw, M.D.,1945). Nowadays, coccidiosis is prevented by anticoccidial drugs that are added to food, but continuously usage of these drugs will leads to unavoidably emergence of resistant Eimeria strains (Jeurissen SH,à Janse EM,à Vermeulen AN,à Vervelde L, 1996). This prolonged use of drugs have many side effects such as decrease fertility (Joyner, 1964) and encourage to the development of drug-resistant strains (McLoughlin and Gardiner, 1963). It will also interfere with immunity (Davies and Kendall, 1955; Reid, 1960), Moreover, the present drugs that available do not offer effective protection against all Eimeria parasitic species in chickens and most of the current coccidiostats are not suitable to use for prolonged periods intended for human consumption. In spite of the high efficacy of modern coccidiostats, upsurge of coccidiosis may occur due to high levels of contamination in the environment, the development of drug-resistance strains as well as reduced the usage of the drug and a high de gree of susceptibility (Joyner, 1970). 1.2 OBJECTIVES To amplify and sequence the surface antigen from apicomplexan parasite, Eimeria Tenella. To clone the surface antigen of apicomplexan parasite, Eimeria Tenella. 2.0 LITERATURE REVIEW 2.1 APICOMPLEXAN PARASITES The Apicomplexa are a phylum from the group of diverse obligate intracellular parasites containing Toxoplasma gondii and Cryptosporidium parvum which are the opportunistic pathogens of immunocompromised individuals, Plasmodium spp., the parasites that cause malaria and also Eimeria spp. and the Theileria spp., the parasites that consider as agricultural importance(Naomi S. Morrissette andà L. David Sibley, 2002). Parasitic protozoans of the apicomplexa are the most frequentt and successful pathogens known to the world. Infection by this parasites causes incalculable morbidity and mortality to humans and agricultural animals(Aikawa, M, 1988). Presently, more than 50 billion livestock for food production especially for the poultry, suffer from debilitating intestinal diseases that caused by many species of apicomplexan parasites such as Eimeria, Theileria, and Babesia (Tomley and Shirley, 2009). Besides, half of the worldââ¬â¢s population is at risk of getting malaria that caused by Plasmodium species (Guerra et al., 2006). Eimeria is the cause of of coccidiosis in chickens while Theileria, the cattle parasite is characterized by anemia and high death rate especially in pregnant cows. Plasmodium infects red blood cells in bird species and cause malaria as well as in several other vertebrate including human. In Africa, almost one million human died because of malaria each year, which mean that a child dies every 30 seconds of this disease (Coombs and Muller, 2002; Shirley et al., 2005). All of those apicomplexan parasites share distinguishing morphological features, cytoskeleton organization and the way of motility, invasion and also replication(Naomi S. Morrissette andà L. David Sibley, 2002). These parasites have an elongated shape and a clearly visible specialization of the apical region (Aikawa,M., 1998). Many of the distinct characteristics compose of a collection of unique organelles termed the apical complex(Naomi S. Morrissette andà L. David Sibley, 2002). Theapical complexis the flag trait required for classification asApicomplexa (Lee et al., 2000, Levine, 1973). It is a components found at the anterior end of certain stages, most notably at the infective stages, replacing the nucleus and mitochondria towards the posterior end (Aikawa et al., 1978). Upon contact with a suitable host cell, apicomplexans can invade within seconds, with minimal apparent disturbance of the infected cell (Boris Striepenmail, Carly N Jordan, Sarah Reiff, Giel G van Dooren, 2 007). Figure 2.1 : The morphology of apicomplexan parasites Copyrightà © 2002, American Society for Microbiology 2.2 THE ROLE OF GLIDING MOTILITY OF THE APICOMPLEXA IN CELL INVASION The members of Apicomplexa invade host cell by substrate-dependent forward locomotion known as gliding motility(Pinder et al., 2000; Opitz Soldati, 2002). Apicomplexa does not possess cilic, flagella, type IV pili or other locomotory organelles (Russell Sinden,1981), nor do they crawl like amoeba (Mitchison Cramer, 1996) or deform their membrane. The gliding movement is actinââ¬âmyosin motor dependent (Hakansson et al.,1998; Pinder et al., 2000)which coupled with the substratum, presumably by transmembrane proteins such as circumsporozoite-and-TRAP related protein (CTRP) and thrombospondin-related adhesive protein (TRAP) which have cytoplasmic sequences (Menard, 2000). Motility can be visualized in real time with video microscopy (Russell Sinden, 1981; Morisaki et al., 1995) or by the formation of surface membrane traits that can be labelled with immunofluorescence assays (Arrowood et al., Stewart Vanderberg, 1988; Hakansson et al., 1999). Circular gliding occurs when a paras ite lies on its right side(where the apex is defined as the top of the parasite and dorsal is defined as the convex surface of the parasite) and moves around in a counter clockwise circle. Upright twirling takes place when a parasitic stands on its posterior and spins in a clockwise circle. Furthermore, helical gliding occurs when the parasite begins on its left side and initiates a clockwise revolution around its long axis while moving forward one body length. The parasite then flips onto its left side while undergoing little forward motility. Helical gliding allows a curved parasite to propel itself straight across substrate (Hakansson et al., 1999). Host-cell invasion by apicomplexan parasites involves the successive exocytosis of three different secretory organelles which are micronemes, rhoptries and dense granules. Rhoptries, dense granule and micronemes are unique secretory organelles containing the products that need for motility, adhesion to host cells, invasion of host cells, and formation of the parasitophorous vacuole (N. S. Morrissette, A. Mitra, D. Sept and L. D. Sibley, 2004). Micronemes are used for host-cell recognition, binding, and possibly motility. Rhoptries are used for parasitophorous vacuole formation whilst dense granules used for remodeling the vacuole into a metabolically active compartment (Dubremetz JF et al., 1998). Attachment to the host cell is started via interaction of the surface protein of the parasites with the plasma membrane of the host cell(Grimwood and Smith, 1996). The apical region of the infecting parasite which is called zoite connects to the host cell, creating a depression in the cell plasma membrane and taking the shape of the zoite while forming a condensed, electron-dense area at the point of attachment (Aikawa et al., 1978). Rhoptry ducts extend from the apical complex and through the junction formed between the two cells (Aikawa et al., 1978). This step is proceed by the microneme and rhoptry that release vast array proteins which have the capacity to encourage formation of the protective parasitophorous vacuole that surrounds the parasite once inside the host cell (Bannister and Mitchell, 1989). As conclusion, the actual invasion of the parasite is intervene by the formation of a moving junction around the infecting parasite which is so named because it moves along the len gth of the parasite resulting in the engulfment of the parasite within the host cell (Besteiro et al., 2009). Figure 2.2 : Current model of the motor protein complex driving gliding motility. (Adapted from Soldati et al (2004) Current Opinion in Cell Biology 16, 32-40.) 2.3 EIMERIA TENELLA Eimeria Tenellais one of seven species that cause coccidiosis in chickens (Shirley MW, Smith AL, Tomley FM, 2005). It is one of the most pathogenicEimeriaspp. that inflicts economic losses on the poultry industry all over the world (Dalloul RA, Lillehoj HS, 2006). Eimeria tenella can be found in the feces of the infected chicken (Michael G. Wallach mail, Udi Ashash, Amnon Michael, Nicholas C. Smith, 2008) and they have complex developmental life cycles with an exogenous phase in the environment during which oocysts excreted from the chicken undergo sporulation and become infective while the endogenous phase in the intestine during which there are two or more rounds of discrete depending on the species, expansive asexual reproduction (schizogony) followed by sexual differentiation, fertilization and shedding of unsporulated oocysts (Kalpana Lal, Elizabeth Bromley, Richard Oakes, Judith Helena Prieto, Sanya J Sanderson, Dominic Kurian, Lawrence Hunt, John R Yates, III, Jonathan M Wastl ing, Robert E Sinden, Fiona M Tomley, 2009). The unsporulated oocyst will develops by the deposition of proteinsfrom two visible wall forming bodies becoming a multi-layered oocyst cell wall (Ferguson DJ, Belli SI, Smith NC, Wallach MG, 2003). After shedding, the unsporulated oocysts will make contact with moisture and air then rapidly undergo meiosis and mitosis to produce 8 haploid sporozoites (Ryan R, Shirley M, Tomley F, 2000). In the case of Emeria tenella, sporozoites will migrate to the caecum where they invade villus enterocytes and undergo their entire endogenous development within enterocytes of the crypts (Rose ME, Lawn AM, Millard BJ, 1984). Eimeria tenellaundergoes two distinct and massive waves of schizogony in the crypts, which produce large numbers of first and second generation merozoites. A third round of schizogony, begin by invasion of second generation merozoites and characterized by much smaller schizonts, is known to occur and may be mandatory although it is possible that invasion of second generation mer ozoites can also initiate gametogony (McDonald V, Rose ME, 1987). Sporozoites and merozoites ofEimeria tenellahave many features related to their invasive natures including micronemes that release protein, which are very important for host binding and invasion (Periz J, Gill AC, Hunt L,Brown P,Tomley FM, 2007) , the use of actin based ââ¬Ëglideosomeââ¬â¢ to power up the host invasion(Bumstead J, Tomley F,2000) and the secretion of rhoptry proteins to form the parasitophorous vacuole within which the parasite resides during the invasion (Greif G, Entzeroth R,1996). As a conclusion, the life cycle can be divided into three distinct phases which include sporogony (the unsporulated oocysts shed in the faeces of the host undergo sporulation in the environment to become infective), schizogony (an expansive form of asexual reproduction) and a sexual phase, gametogony (which leads to the formation of female and male gametes and terminates with the formation of oocysts) (Shirley Schnitzler, 1999). Figure 2.3 : The life cycle of Eimeria (United States Department of Agriculture (USDA) 2.4 SURFACE ANTIGEN Surface antigens are those expressed on the surface of infected cells that can induce a cytotoxic phenomenon leading to a destruction of host cells or to activation of the killing mechanism in the host cell itself. However, little is known about their role in parasite development (Tabarà ©s et al., 2004). Some of these surface antigens have been associated with a variety of functions in host cell invasion, pathogenicity as well as the immune avoidance and also known to draw out strong immune responses (Jung C, Lee CYF, Grigg M, 2004). Many research has been carried out to study the role of surface antigens in the growth, development, and also the survival of the parasites. Glycosylphosphatidylinositol (GPI)-anchored surface antigens (SAGs) of Eimeria Tenellaare among the major surface molecules of the parasite and many of the SAGs are expressed during the development of second generation merozoitesmaking them good targets for host innate and adaptive immune responses. Other apicompl exan parasites such as Plasmodium falciparum,à Sarcocystis neuronaand Toxoplasma gondii also have the GPI-linked antigens expressed on their surfaces (Gilson PR, Nebl T, Vukcevic D, Moritz RL, Sargean T, 2006). Besides, SAG proteins may be used by Eimeria tenellato confuse the host immune system and improve the survival of the parasites. The chicken immune response might be misdirect towards the antibody production because of the simultaneous expression of multiple SAG proteins rather than the cellular mediated immune responses required to eliminateEimeria Tenella, therefore, allowing the parasites to avoid the first line defense mechanisms of the host and multiply more easily (Yock-Ping Chow, Kiew-Lian Wan, Damer P. Blake, Fiona Tomley, Sheila Nathan, 2011).
Wednesday, November 13, 2019
Lucas: King Of Film :: essays research papers fc
Lucas: King of Film Whether it be through his epic Star Wars saga, or through the exalted special effects crew he pioneered, Industrial Light and Magic, he continues to amaze audiences world wide. His name in synonymous with famous directors/producers in the world. His impacts reach out in more fields than just film. He has created companies that produce award winning video games, toy companies produce action figures designed after characters from his movies, many books by many authors based on his original film stories, and countless other wings of Lucas' reign exist in today's world. Since his youth, George Lucas has experienced many influences, which in turn push him to make the greatest contributions to the film industry which leave an ever increasing impact on film today and the world. Throughout history, it is apparent that those who are recognized as "great ones" were influenced in some way or another to become the leader who they are. In George Lucas' case, he was greatly influenced in his late teens and early twenties. Lucas claims to have chased girls and raced cars throughout high school, and barely made it through (Moritz 258). Soon after high school, Lucas attended Modesto Junior College in California and continued to work on cars as his main interest (Moritz 258). In Smith, Lucas is quoted saying, "I was a hell-raiser; lived, ate, breathed cars! That was everything for me"(84). Lucas even worked on pit crews for race cars when he met Haskell Wexler, who introduced him to film (Moritz 258). Eventually Lucas realized his new passion was film. Mr. Wexler helped Lucas gain admission into the University of Southern California's film department (Moritz 260). In college Lucas was the head of his film classes winning many awards and accolades. His first feature movie in college was titled THX-1138 and won his university's award for best film (Moritz 259). Lucas is also inspired by his circle of friends and fellow directors, producers, and collaborations with them. With the success of THX-1138 at the university, Lucas was awarded the chance to be an observer on the set of Finian's Rainbow directed by University of Southern California alumnus Francis Ford Coppola (Champlin 7). Soon the two began to chat, and then became friends, so Coppola let Lucas work for him on the movie. With his hard work, Lucas earned the respect of Coppola who in turn did Lucas the favor of convincing producers to let Lucas direct a major motion picture (Moritz 7). Lucas' first major motion picture was American Graffiti, with this film Coppola had given Lucas the chance to make a foothold in the film industry, and he certainly did.
Monday, November 11, 2019
Nitration of Methyl Benzoate
Nitration of Methyl Benzoate Introduction: Nitration is an example of an electrophile aromatic substitution reaction, where nitro (NO2) group is being substituted for a hydrogen on an aromatic compound. This is achieved by the formation of the nitronium ion by protonation of nitric acid from sulfuric acid. The zirconium ion is a strong electrophile and can react with aromatic compound such as Methyl benzoate to form an arenium ion intermediate. The arenium ion is then depronated to reform the aromatic ring and yield the final product with the newly attached nitro group.Reaction: ? Table of Physical Contents: Procedure: Obtain an ice bath. 12 ml of concentrated sulfuric acid was gathered, cooled to 0 degrees Celsius, and put in a 125-ml Erlenmeyer flash. Then 6. 1g of methyl benzoate was added. Then cooled in an ice bath to 0-10 degrees Celsius. A Pasteur pipette was used to add a cooled mixture of 4-mL of concentrated sulfuric acid and 4-mL of concentrated nitric acid. ? Figure 1: H ow to properly use a Pasteur pipette The mixture was then swirled frequently and maintained a temperature of 5C-15C. Figure 2: Swirling the mixture After all of the nitric acid was added the mixture was then warmed to room temperature. After 15 minutes, it was then poured into a 250-mL. The solid product was isolated by suction filtration using a small Buchner funnel. ? Figure3: Labeled vacuum filtration ? Figure 4: Carefully scraping out the crystals A small amount of sample was saved and weighed. Results: ? Figure 5: NMR of the product ? Discussion/Conclusion: The melting point of the recrystallized product was 73-78 degrees Celsius.This was very accurate to that of the book. In this experiment, methyl benzoate went through an electrophilic substitution reaction to form Mehyl-m-nitro benzoate, where a NO2 group was added to the methyl benzoate in the meta position. Nitric acid is not a strong enough electrophile to react with the aromatic benzene ring, but the zirconium ion with t he positive charge on the nitrogen is a strong electrophile and can react with the double bond of the methyl benzoate. The experiment was an overall success.The H NMR data successfully confirmed that the experiment was done correctly. Substances Formula Weight g/mol Quantity Moles Used Mole Ratio Boiling Point Melting Point Density g/mL Concentrated Nitric Acid 63. 01 0. 5mL 1. 192 x 10^-2 N/A N/A 121 1. 5027 Concentrated Sulfuric Acid 98. 08 1. 6mL 3. 0 x 10^-2 N/A N/A N/A 1. 841 Ethanol 46. 07 2-3mL N/A N/A N/A N/A N/A Methyl Benzoate 136. 15 0. 55g 4. 039x 10^-3 1 to 1 113-115 N/A N/A Methyl Nitro- Benzoate 181. 13 Product N/A N/A N/A N/A N/A
Friday, November 8, 2019
Learning About C# for Beginners
Learning About C# for Beginners C# is a general purpose object-oriented programming language developed at Microsoft and released in 2002. It is similar to Java in its syntax. The purpose of C# is to precisely define a series of operations that a computer can perform to accomplish a task. Most C# operations involve manipulating numbers and text, but anything that the computer can physically do can be programmed in C#. Computers have no intelligence- they have to be told exactly what to do, and their actions are defined by the programming language you use. Once programmed, they can repeat the steps as many times as needed at high speed. Modern PCs are so fast they can count to a billion in seconds. What Can a C# Program Do? Typical programming tasks includeà putting data into a database or pulling it out, displaying high-speed graphics in a game or video, controlling electronic devices attached to the PC and playing music or sound effects. You can even use it to write software to generate music or help you compose. Some developers believe that C# is too slow for gamesà because it is interpretedà rather than compiled. However the .NET Framework compiles the interpreted code the first time it runs. Is C# the Best Programming Language? C# is a highly ranked program language. Many computer languages are written for a specific purpose, but C# is a general purpose language with features to make programs more robust.à Unlike C and to a lesser extent Java, the screen handling in C# is excellent on both desktops and the web. In this role, C# overtook languages such as Visual Basic and Delphi. Which Computers Can Run C#? Any PC that can run the .NET Framework can run the C# programming language. Linux supports C# using the Mono C# compiler. How Do I Get Started With C#? You need a C# compiler. There are a number of commercial and free ones available. The professional version of Visual Studio can compile C# code. Mono is a free and open-source C# compiler. How Do I Begin Writing C# Applications? C# is written using a text editor. You write a computer program as a series of instructions (called statements) in a notation that looks a little like mathematical formulas. This is saved as aà text file and then compiled and linked to generate machine code which you then can run. Most applications you use on a computer were written and compiled like this, many of them in C#. Is There Plenty of C# Open Source Code? Not as much as in Java, C or C but it is starting to become popular. Unlike commercial applications, where the source code is owned by a business and never made available, open source code can be viewed and used by anyone. Its an excellent way to learn coding techniques. The Job Market for C# Programmers There are plenty of C# jobs out there, and C# has the backing of Microsoft, so is likely to be around for a while.à You could write your own games, but youd need to be artistic or need an artist friend because you also need music and sound effects. Perhaps youd prefer a career as a business software developer creating business applications or as a software engineer.
Wednesday, November 6, 2019
Chapter 9 A.P U.S History Essay Example
Chapter 9 A.P U.S History Essay Example Chapter 9 A.P U.S History Essay Chapter 9 A.P U.S History Essay Chapter 9 Essay Although President Jackson was a champion of democracy and egalitarianism, there are some instances where he takes advantage of his presidential powers and uses him for his own benefits and beliefs and not for the good of the country. President Jackson did a lot of good for the early Democratic Party though. He helped expand voting and focused on destroying monopolies like the national bank that he believed were harming the nation. He did however take manners into his own hands at times. For instance disregarding Supreme Court rulings. Enacting Military action on a state and Vetoing bills like the Maysville road that wouldVe helped the union, but since he didnt approve he vetoed it. President Jackson did a fantastic Job of expanding democracy. In his presidency he expanded the amount of voters from 27% in the election of 1824 to 58% in 1828 and by 1840 80% of adult white males were voting. Jackson thoroughly believed in equal protection and equal benefits, and that is the form of government he wanted. During Jacksons administration he believed in taking owers away from the rich and giving the common man more of it. In the Picture Jackson Tramples on the Constitution he is depicted as a monarchial king who tramples on the constitution and is called King Andrew the First. (Document A). This is because the opposing political party the Whigs wanted to keep power in the hand of the rich to create a more stable form of government and by Jackson vetoing the bill they thought he was abusing his Presidential Powers. Furthermore there were some instances where Jackson did abuse his political powers by blatantly disregarding the Constitution. In the case Worcester vs. Georgia. Cherokee Indians fought for their right to control their land which was roughly h the size of Georgia. We have a perfect and original right to remain in our lands without interruption or molestation. (Document B) Georgia fought to have them removed saying that they were uncivilized and couldnt assimilate into American culture, and that they made a contract with tribe leaders. In the case the Supreme Court ruled in favor of Worcester and the Cherokees. John Marshall said The Cherokee Indians have an unquestionable right to their territory until title should be extinguished by voluntary cession to the United States (Document B). Jackson disregarded this ruling and had the Indian Removal Act of 1830 put in place where he forced the Indians west of the Mississippi River along what is now known as The Trail of Tears. Furthermore although Jackson had his flaws he was still a great promoter of democracy and preserved the Union. In 1828 when the Tariff of Abomination was put into place the eople of South Carolina felt the tariffs were too high and would destroy their businesses. In response to this tariff The South Carolina Exposition and Protest was written. (Document E). This document said that Tariff acts are unconstitutional and that the State of South Carolina would consider them nullified and not obey them. Jacksons response to this was the Force Act which gave the President a right to use any means necessary to get people to obey the constitution. Although this didnt solve the crisis it showed Jackson wanted to preserve the union over all else. The reduced over 10 years to the old 1816 tariffs which was considered more moderate. In conclusion Jackson was an excellent President who was a champion of democracy and egalitarianism. He expanded political power to the common man and fought against a corporate monopoly which he felt was destroying the Union, the National Bank. Jackson did have his faults though he would override rulings and do what he saw fit. He would veto many bills despite what was right. Jackson had his issues but he was one of the greatest expanders of Democracy in our history.
Monday, November 4, 2019
Alternative Strategies to Combating Poverty Essay
Alternative Strategies to Combating Poverty - Essay Example The minimum wage should be raised to over $11 per hour. The majority of poor Americans are workers that sustain their households on very small salaries. The senate should pass a minimum wage, which guarantees the dignity desired by all households. Every worker needs to make wages that enable them to have decent lives. A minimum wage that is more than $11 an hour can guarantee the dignity desired by all people. It is because no employer will be allowed to pay miserable wages to workers, regardless of their efficiency situations. There should be a minimum wage and overtime protections for the care workers. The income of most home care workers is way below the minimum wage, yet they are among the biggest occupations in the US today. The Obama administration had in December 2011 promised to liberate 2.5 million care workers from poverty, but this has remained a long-awaited promise. Projections show that in the next decade, the demand for care workers will rise by 1.3 million. A new set of regulations should be devised and implemented by the government to provide a federal minimum wage and overtime protections for most home care aides. The government should invest more in the subsidized and transitional jobs. Many jobless people have little education and skills to cope with the stiff job market. Despite the recovery of the economy in America, about two in every five jobless people have been unemployed for at least six months. About 6.7 million young people are out of school and are not of working.
Saturday, November 2, 2019
Reasons for Quarrels between Friends Essay Example | Topics and Well Written Essays - 750 words
Reasons for Quarrels between Friends - Essay Example .. severe and demonstrate a lack of trust and respect. In these cases, a firm break up may be the right answer. ââ¬Å"She goes on to explain the reasons as to why friends could end up arguing and what the end result of that action brings for the parties concerned. As we grow up, we come to realize that we may have a lot of friends, but only one whom we feel deeply close and connected to. That person is termed as a best friend. A best friend is someone whom we share our inner most thoughts and feelings with. That friend is the physical representation of the trust that we have learned to share with other people. Then something happens, your best friend betrays you for some reason. The betrayal could be something as petty as telling your parents about the day that you skipped school to go see a movie or something major (as in the case of adults) that resulted in the breaking of the trust because your best friend told someone else about your secret or, in some cases, started some gossip about you based upon the secrets that you told her. Whatever the reason, the trust you gave that person was broken. The betrayal you feel can be so severe that arguing with your friend does not produce a healthy solution to the situation. Sometimes the only logical path for your relationship to take with that person is to end the friendship since the sense of betrayal is sometimes overwhelming. Other times the reason for the break-up or quarrel in a friendship stems from the lack of support from people whom you expected to have your back during rough patches of your life. Say for example you move to a new school but still live in the same neighborhood. Your classmates used to be the same kids who lived on the same block. Now, you have a totally new set of classmates whom you have to adjust to because the new school standards and social set up is a far cry from your old one. When you get home, you expect to see your neighbors, whom you consider to be friends, and spend time with the m. Sharing your thoughts and feelings and just letting them know how hard it is to adjust to your new set up. However, instead of lending you an ear and offering you a shoulder to cry on, your friend or friends choose instead to make a joke out of your situation and make you feel like an outsider within a group of people whom you thought were your friends. This lack of support can often be a major cause of friction between friends that could also lead to the breakup of friendships if the problem is not resolved in time. Oftentimes such cases of lack of friend support are just a minor reason for arguments between friends and, if caught in time, the friendship can actually still be mended. Let's not forget, arguments between friends can also be caused by petty jealousy over things as simple as who looked better in an outfit, or who got the higher grade in a test. This feeling of inferiority between friends often results in the jealous friend acting all unreasonable and mean towards th e other friend who is deemed to have gotten the better result in a given situation. This failure to be happy for the success of other friends is a major cause of arguments between friends but can usually be ironed out in the end with a simple explanation. Jealousy does not often result in the end of
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